Hydrogen-Bond-Assisted Chalcogen Transfer between Phosphine Selenides and Arsine Oxides

URN to cite this document:: urn:nbn:de:bvb:355-epub-768158
DOI to cite this document:: 10.5283/epub.76815

Krutin, Danil V. ; Tsybulin, Semyon V. ; Mulloyarova, Valeriya V. ; Tupikina, Elena Yu.

; Tolstoy, Peter M.

; Antonov, Alexander S.

License: Creative Commons Attribution 4.0
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Date of publication of this fulltext: 02 Jun 2025 13:05

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Abstract

The Brønsted acid catalysis is widely regarded as one of the most effective methods for activating inert substrates and enabling unique reactivity. In this work, we introduce the first example of H-bond-assisted chalcogen exchange between arsine oxides and phosphine selenides under mild conditions, providing a powerful approach to the synthesis of arsine selenides. The reaction proceeds ...