Direkt zum Inhalt

Jagode, Rupert P. M. ; Scrimgeour, Alexander ; Schlaghaufer, Florian ; Fischer, Johannes ; Slenczka, Alkwin

Fingerprint of Droplet Shape and Vortex in the Line Shape at the Electronic Band Origin of Phthalocyanine in Superfluid Helium Droplets

Jagode, Rupert P. M., Scrimgeour, Alexander, Schlaghaufer, Florian, Fischer, Johannes und Slenczka, Alkwin (2025) Fingerprint of Droplet Shape and Vortex in the Line Shape at the Electronic Band Origin of Phthalocyanine in Superfluid Helium Droplets. ACS Physical Chemistry Au.

Veröffentlichungsdatum dieses Volltextes: 04 Sep 2025 16:00
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.77653


Zusammenfassung

X-ray and XUV diffraction experiments have visualized both the outer shape and quantum vortices inside individual superfluid helium droplets. Both features are effective on the helium induced signature observed as the spectral shape and position of the electronic transitions of molecules doped into helium droplets. In this article the helium induced signature at the electronic band origin of ...

X-ray and XUV diffraction experiments have visualized both the outer shape and quantum vortices inside individual superfluid helium droplets. Both features are effective on the helium induced signature observed as the spectral shape and position of the electronic transitions of molecules doped into helium droplets. In this article the helium induced signature at the electronic band origin of phthalocyanine is re-examined systematically comprising previous analytical results as well as newly reported experimental investigations. Helium-induced effects such as a nonmonotonous evolution of the solvent shift and the emergence of an optical anisotropy, both observed for rather large helium droplets, are the spectroscopic response on the analytical results reported from diffraction experiments. All helium induced spectroscopic features can be explained as an expression of London dispersion interaction under the varying structural conditions of helium droplets.



Beteiligte Einrichtungen


Details

DokumentenartArtikel
Titel eines Journals oder einer ZeitschriftACS Physical Chemistry Au
Verlag:American Chemical Society (ACS)
Datum7 August 2025
InstitutionenChemie und Pharmazie > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof Dr. Alkwin Slenczka
Identifikationsnummer
WertTyp
10.1021/acsphyschemau.5c00018DOI
Stichwörter / Keywordsmicrosolvation; superfluid helium nanodroplets; vortex; phthalocyanine; electronic spectroscopy
Dewey-Dezimal-Klassifikation500 Naturwissenschaften und Mathematik > 540 Chemie
StatusVeröffentlicht
BegutachtetJa, diese Version wurde begutachtet
An der Universität Regensburg entstandenJa
URN der UB Regensburgurn:nbn:de:bvb:355-epub-776534
Dokumenten-ID77653

Bibliographische Daten exportieren

Nur für Besitzer und Autoren: Kontrollseite des Eintrags

nach oben