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Jagode, Rupert P. M. ; Scrimgeour, Alexander ; Schlaghaufer, Florian ; Fischer, Johannes ; Slenczka, Alkwin

Fingerprint of Droplet Shape and Vortex in the Line Shape at the Electronic Band Origin of Phthalocyanine in Superfluid Helium Droplets

Jagode, Rupert P. M., Scrimgeour, Alexander, Schlaghaufer, Florian, Fischer, Johannes and Slenczka, Alkwin (2025) Fingerprint of Droplet Shape and Vortex in the Line Shape at the Electronic Band Origin of Phthalocyanine in Superfluid Helium Droplets. ACS Physical Chemistry Au.

Date of publication of this fulltext: 04 Sep 2025 16:00
Article
DOI to cite this document: 10.5283/epub.77653


Abstract

X-ray and XUV diffraction experiments have visualized both the outer shape and quantum vortices inside individual superfluid helium droplets. Both features are effective on the helium induced signature observed as the spectral shape and position of the electronic transitions of molecules doped into helium droplets. In this article the helium induced signature at the electronic band origin of ...

X-ray and XUV diffraction experiments have visualized both the outer shape and quantum vortices inside individual superfluid helium droplets. Both features are effective on the helium induced signature observed as the spectral shape and position of the electronic transitions of molecules doped into helium droplets. In this article the helium induced signature at the electronic band origin of phthalocyanine is re-examined systematically comprising previous analytical results as well as newly reported experimental investigations. Helium-induced effects such as a nonmonotonous evolution of the solvent shift and the emergence of an optical anisotropy, both observed for rather large helium droplets, are the spectroscopic response on the analytical results reported from diffraction experiments. All helium induced spectroscopic features can be explained as an expression of London dispersion interaction under the varying structural conditions of helium droplets.



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Details

Item typeArticle
Journal or Publication TitleACS Physical Chemistry Au
Publisher:American Chemical Society (ACS)
Date7 August 2025
InstitutionsChemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Alkwin Slenczka
Identification Number
ValueType
10.1021/acsphyschemau.5c00018DOI
Keywordsmicrosolvation; superfluid helium nanodroplets; vortex; phthalocyanine; electronic spectroscopy
Dewey Decimal Classification500 Science > 540 Chemistry & allied sciences
StatusPublished
RefereedYes, this version has been refereed
Created at the University of RegensburgYes
URN of the UB Regensburgurn:nbn:de:bvb:355-epub-776534
Item ID77653

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