The formation of Lewis acid/base stabilised phosphanyltrielanes – A theoretical and experimental study - University of Regensburg Publication Server

DOI to cite this document:: 10.5283/epub.15187

Vogel, Ulf ; Timoshkin, Alexey Y. ; Schwan, Karl-Christian ; Bodensteiner, Michael ; Scheer, Manfred

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Date of publication of this fulltext: 07 Jun 2010 12:59

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Abstract

Theoretical investigations on the thermochemistry and the reaction mechanism of the formation of Lewis acid/base stabilised phosphanyltrielanes D · H2EPH2 · A (D = Lewis base, A = Lewis acid) were conducted. The reactions of EH3 · D with A · PH3 to form D · H2EPH2 · A and H2 (E = B, Al, Ga; D = NH3; A = BH3, Cr(CO)5) are all exothermic, regardless of whether donors and acceptors are present or ...