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Lewis Base Stabilized Phosphanylborane

Schwan, Karl-Christian, Timoshkin, Alexey Y., Zabel, Manfred and Scheer, Manfred (2006) Lewis Base Stabilized Phosphanylborane. Chemistry - A European Journal 12 (18), pp. 4900-4908.

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The abstraction of the Lewis acid from [W(CO)5(PH2BH2NMe3)] (1) by an excess of P(OMe3)3 leads to the quantitative formation of the first Lewis base stabilized monomeric parent compound of phosphanylborane [H2PBH2NMe3] 2. Density functional theory (DFT) calculations have shown a low energetic difference between the crystallographically determined antiperiplanar arrangement of the lone pair and ...


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Item type:Article
Date:27 April 2006
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Keywords:boron; density functional calculations; Lewis bases; phosphorus
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Created at the University of Regensburg:Unknown
Item ID:15206
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