Go to content
UR Home

Lewis Base Stabilized Phosphanylborane

DOI to cite this document:
Schwan, Karl-Christian ; Timoshkin, Alexey Y. ; Zabel, Manfred ; Scheer, Manfred
(364kB) - Repository staff only
Date of publication of this fulltext: 07 Jun 2010 12:59


The abstraction of the Lewis acid from [W(CO)5(PH2BH2NMe3)] (1) by an excess of P(OMe3)3 leads to the quantitative formation of the first Lewis base stabilized monomeric parent compound of phosphanylborane [H2PBH2NMe3] 2. Density functional theory (DFT) calculations have shown a low energetic difference between the crystallographically determined antiperiplanar arrangement of the lone pair and ...


Owner only: item control page
  1. Homepage UR

University Library

Publication Server


Publishing: oa@ur.de
0941 943 -4239 or -69394

Dissertations: dissertationen@ur.de
0941 943 -3904

Research data: datahub@ur.de
0941 943 -5707

Contact persons