![]() | PDF (148kB) - Repository staff only |
- DOI to cite this document:
- 10.5283/epub.15458
Alternative links to fulltext:DOI
Abstract
Thermolysis of the arsenidene complex [Cp*As{W(CO)5}2] (1) gave [Cp*(CO)2W(η3-As3)] (2), [{W(CO)3Cp*W}2(μ3-As)4] (3), and [{W(CO)3Cp*W}2(μ3-As)3{μ3-AsW(CO)5}] (4). The products show that 1 has undergone a Cp* migration from the σ-bound state at the As atom to η5 coordination at the transition metal, presumably via an intermediate of the type [Cp*(CO)2WAs→W(CO)5]. In a second transformation ...

Owner only: item control page