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- URN to cite this document:
- urn:nbn:de:bvb:355-epub-158744
- DOI to cite this document:
- 10.5283/epub.15874
Abstract
The absol. configuration of a Ciramadol analogue obtained from (-)-menthone is established by 'H-NMR-. simulated NMR-, COSY-90-, and NOEmeasurements. The final compound 2-(a-1 -pyrrolidino)benzy 1-4-isopropyl- 1 -methyl-cyclohexan-3-one (4b), e.g.. has 1R.2S,4S.l IS-configuration due to stereoselective Michael-type addition of pyrrolidine to the pertinent benzylidene intermediate 3. Die absol. ...
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