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Synthesis and structure of cationic guanidinate-bridged bimetallic {Li7M} cubes (M = Mn, Co, Zn) with inverse crown counter anions

Woodruff, D., Bodensteiner, Michael, Sells, D. O., Winpenny, Richard. E. P. and Layfield, Richard A. (2011) Synthesis and structure of cationic guanidinate-bridged bimetallic {Li7M} cubes (M = Mn, Co, Zn) with inverse crown counter anions. Dalton Transactions 40, pp. 10918-10923.

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Abstract

The reactions of the heteroleptic lithium amide [Li3(μ-hmds)2(μ,μ-hpp)] (1), where [hmds]− = hexamethyldisilazide and [hpp]− = hexahydropyrimidopyrimidide, with MnCl2, CoCl2 or ZnBr2 result in the formation of the separated ion-pairs [MLi7(μ8-O)(μ,μ-hpp)6]+[A]−, which each consist of a {MLi7} oxo-centred cube structural motif (M = Mn 2, Co 4, Zn 5), with each face of the cube being bridged by an ...

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Item type:Article
Date:2011
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1039/C1DT10999EDOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:34120
Owner only: item control page

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