Go to content
UR Home

Structural and thermodynamic properties of molecular complexes of aluminum and gallium trihalides with bifunctional donor pyrazine: decisive role of Lewis acidity in 1D polymer formation

URN to cite this document:
DOI to cite this document:
Sevastianova, T. N. ; Bodensteiner, Michael ; Lisovenko, A. S. ; Davydova, E. I. ; Scheer, Manfred
License: Allianz- bzw. Nationallizenz
PDF - Published Version
Date of publication of this fulltext: 04 Aug 2016 08:44


Solid state structures of group 13 metal halide complexes with pyrazine (pyz) of 2 : 1 and 1 : 1 composition have been established by X-ray structural analysis. Complexes of 2 : 1 composition adopt molecular structures MX3·pyz·MX3 with tetrahedral geometry of group 13 metals. Complexes of AlBr3 and GaCl3 of 1 : 1 composition are 1D polymers (MX3·pyz)∞ with trigonal bipyramidal geometry of the ...


Owner only: item control page
  1. Homepage UR

University Library

Publication Server


Publishing: oa@ur.de
0941 943 -4239 or -69394

Dissertations: dissertationen@ur.de
0941 943 -3904

Research data: datahub@ur.de
0941 943 -5707

Contact persons