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Structural and thermodynamic properties of molecular complexes of aluminum and gallium trihalides with bifunctional donor pyrazine: decisive role of Lewis acidity in 1D polymer formation

Sevastianova, T. N., Bodensteiner, Michael, Lisovenko, A. S., Davydova, E. I. and Scheer, Manfred (2013) Structural and thermodynamic properties of molecular complexes of aluminum and gallium trihalides with bifunctional donor pyrazine: decisive role of Lewis acidity in 1D polymer formation. Dalton Transactions 42, pp. 11589-11599.

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Abstract

Solid state structures of group 13 metal halide complexes with pyrazine (pyz) of 2 : 1 and 1 : 1 composition have been established by X-ray structural analysis. Complexes of 2 : 1 composition adopt molecular structures MX3·pyz·MX3 with tetrahedral geometry of group 13 metals. Complexes of AlBr3 and GaCl3 of 1 : 1 composition are 1D polymers (MX3·pyz)∞ with trigonal bipyramidal geometry of the ...

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Item type:Article
Date:2013
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1039/c3dt50954kDOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:34233
Owner only: item control page

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