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Air-sensitive Photoredox Catalysis Performed under Aerobic Conditions in Gel Networks

Häring, Marleen ; Abramov, Alex ; Okumura, Keisuke ; Ghosh, Indrajit ; König, Burkhard ; Yanai, Nobuhiro ; Kimizuka, Nobuo ; Díaz Díaz, David



Abstract

In this work, we demonstrate that useful C-C bond-forming photoredox catalysis can be performed in air using easily prepared gel networks as reaction media to give similar results as are obtained under inert atmosphere conditions. These reactions are completely inhibited in homogeneous solution in air. However, the supramolecular fibrillar gel networks confine the reactants and block oxygen ...

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