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Air-sensitive Photoredox Catalysis Performed under Aerobic Conditions in Gel Networks

Häring, Marleen, Abramov, Alex, Okumura, Keisuke, Ghosh, Indrajit, König, Burkhard, Yanai, Nobuhiro, Kimizuka, Nobuo and Díaz Díaz, David (2018) Air-sensitive Photoredox Catalysis Performed under Aerobic Conditions in Gel Networks. The Journal of Organic Chemistry 57, pp. 7928-7938.

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Abstract

In this work we demonstrate that useful C–C bond forming photoredox catalysis can be performed in air using easily-prepared gel networks as reaction media to give similar results as are obtained under inert-atmosphere conditions. These reactions are completely inhibited in homogeneous solution in air. However, the supramolecular fibrillar gel networks confine the reactants and block oxygen ...

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Item type:Article
Date:29 May 2018
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. David Díaz Díaz
Projects:GRK 1626 Chemische Photokatalyse
Identification Number:
ValueType
10.1021/acs.joc.8b00797DOI
Keywords:photoredox catalysis; gel networks
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Partially
Item ID:37393
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