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The Effect of High Hydrostatic Pressure on Hydrogen Bond Scaffolds

URN to cite this document:
urn:nbn:de:bvb:355-epub-436317
DOI to cite this document:
10.5283/epub.43631
Weinbender, Thomas
Date of publication of this fulltext: 06 Sep 2021 08:46


Abstract (English)

In the present PhD thesis, the thiourea-organocatalyzed Michael addition of diethyl malonate to various heteroaromatic nitroolefins has been studied under high-pressure conditions up to 800 MPa, being conducive to enhanced product yields, high reaction rates, and high enantio-selectivity. Elucidating the effects of solvents for maximizing reaction rates and yields has been carried out using the ...

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Translation of the abstract (German)

In der vorliegenden Doktorarbeit wurde die Addition von Diethylmalonat an verschiedenen heteroaromatischen Nitroolefinen unter Hochdruckbedingungen (bis zu 800 MPa) untersucht. Die Verwendung von Hochdruck führte zu einer erhöhten Produktausbeute, kürzeren Reaktionszeiten und einer hohen Enantioselektivität. Mit Hilfe der sogenannten Perturbed-Chain Polar Statistical Associating Fluid Theory ...

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