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Photocatalytic Oxidative [2+2] Cycloelimination Reactions with Flavinium Salts: Mechanistic Study and Influence of the Catalyst Structure

URN to cite this document:
urn:nbn:de:bvb:355-epub-444633
DOI to cite this document:
10.5283/epub.44463
Hartman, Tomáš ; Reisnerova, Martina ; Chudoba, Josef ; Kutta, Roger Jan ; ; ;
Date of publication of this fulltext: 20 Jan 2021 11:09

This publication is part of the DEAL contract with Wiley.


Abstract

Flavinium salts are frequently used in organocatalysis but their application in photoredox catalysis has not been systematically investigated to date. We synthesized a series of 5-ethyl-1,3-dimethylalloxazinium salts with different substituents in the positions 7 and 8 and investigated their application in light-dependent oxidative cycloelimination of cyclobutanes. Detailed mechanistic ...

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