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Photocatalytic Oxidative [2+2] Cycloelimination Reactions with Flavinium Salts: Mechanistic Study and Influence of the Catalyst Structure

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Hartman, Tomáš ; Reisnerova, Martina ; Chudoba, Josef ; Kutta, Roger Jan ; ; ;
Date of publication of this fulltext: 20 Jan 2021 11:09

This publication is part of the DEAL contract with Wiley.


Flavinium salts are frequently used in organocatalysis but their application in photoredox catalysis has not been systematically investigated to date. We synthesized a series of 5-ethyl-1,3-dimethylalloxazinium salts with different substituents in the positions 7 and 8 and investigated their application in light-dependent oxidative cycloelimination of cyclobutanes. Detailed mechanistic ...


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