Go to content
UR Home

Electro-mediated PhotoRedox Catalysis for Selective C(sp3)-O Cleavages of Phosphinated Alcohols to Carbanions

URN to cite this document:
urn:nbn:de:bvb:355-epub-461960
DOI to cite this document:
10.5283/epub.46196
Tian, Xianhai ; Karl, Tobias A. ; Reiter, Sebastian ; Yakubov, Shaboz ; de Vivie-Riedle, Regina ; König, Burkhard ; Barham, Joshua Philip
WarningThere is a more recent version of this item available.
[img]
Preview
License: Creative Commons Attribution 4.0
PDF - Published Version
(1MB)
Date of publication of this fulltext: 29 Jun 2021 07:16

This publication is part of the DEAL contract with Wiley.


Abstract

We report a novel example of electro-mediated photoredox catalysis (e-PRC) in the reductive cleavage of C(sp 3 )-O bonds of phosphinated alcohols to alkyl carbanions. As well as deoxygenations, olefinations are reported which are E -selective and can be made Z -selective in a tandem reduction/photosensitization process where both steps are photoelectrochemically promoted. Spectroscopy, ...

plus


Owner only: item control page
  1. Homepage UR

University Library

Publication Server

Contact:

Publishing: oa@ur.de
0941 943 -4239 or -69394

Dissertations: dissertationen@ur.de
0941 943 -3904

Research data: datahub@ur.de
0941 943 -5707

Contact persons