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Electro-mediated PhotoRedox Catalysis for Selective C(sp3)-O Cleavages of Phosphinated Alcohols to Carbanions

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Tian, Xianhai ; Karl, Tobias A. ; Reiter, Sebastian ; Yakubov, Shaboz ; de Vivie-Riedle, Regina ; König, Burkhard ; Barham, Joshua Philip

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Date of publication of this fulltext: 01 Jul 2022 05:47

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We report a novel example of electro-mediated photoredox catalysis (e-PRC) in the reductive cleavage of C(sp 3 )-O bonds of phosphinated alcohols to alkyl carbanions. As well as deoxygenations, olefinations are reported which are E -selective and can be made Z -selective in a tandem reduction/photosensitization process where both steps are photoelectrochemically promoted. Spectroscopy, ...


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