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The Lewis-Base-Stabilized Diphenyl-Substituted Arsanylborane: A Versatile Building Block for Arsanylborane Oligomers

Hegen, Oliver ; Virovets, Alexander V. ; Timoshkin, Alexey Y. ; Scheer, Manfred


The synthesis and properties of the diphenyl-substituted arsanylborane Ph2AsBH2SMe2 (1) and Ph2AsBH2NMe3 (2) stabilized by a Lewis base (LB) were reported. These compounds were obtained by reaction of KAsPh2 with IBH2-LB (LB=SMe2, NMe3). Compounds 1 and 2 were used as starting materials for oligomeric/ polymeric arsinoboranes. The neutral species, H3B-Ph2AsBH2NMe3 (3) and Br3B-Ph2AsBH2NMe3 (4), ...


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