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Isomerism and dynamic behavior of bridging phosphaalkynes bound to a dicopper complex

Nicolay, Amélie ; Ziegler, Micah S. ; Small, David W. ; Grünbauer, Rebecca ; Scheer, Manfred ; Tilley, T. Don


A dicopper complex featuring a symmetrically bridging nitrile ligand and supported by a binucleating naphthyridine-based ligand, [Cu-2(mu-eta(1):eta(1)-MeCN)DPFN](NTf2)(2), was treated with phosphaalkynes (RC P, isoelectronic analogues of nitriles) to yield dicopper complexes that exhibit phosphaalkynes in rare mu-eta(2):eta(2) binding coordination modes. X-ray crystallography revealed ...


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