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Three‐ and Five‐Membered Anionic Chains of Pnictogenylboranes

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Moussa, Mehdi Elsayed ; Kahoun, Tobias ; Marquardt, Christian ; Ackermann, Matthias T. ; Hegen, Oliver ; Seidl, Michael ; Timoshkin, Alexey Y. ; Virovets, Alexander V. ; Bodensteiner, Michael ; Scheer, Manfred
Date of publication of this fulltext: 29 Mar 2023 08:07

This publication is part of the DEAL contract with Wiley.


An unprecedented family of three- and five-membered substituted anionic derivatives of parent pnictogenylboranes is herein reported. Reacting various combinations of the pnictogenylboranes H2E′−BH2−NMe3 (E′=P, As) with pnictogen-based nucleophiles MER1R2 (E=P, As; R1=H, R2=tBu; R1=R2=Ph; M=Na, K) allows for the isolation of the unsymmetrical products [Na(18-crown-6)][H2E′−BH2−EHtBu] (3: E=E′=P; ...


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