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Synthesis and Reactivity of Hetero‐Pnictogen Diazonium Analogs Stabilized by Transition Metal Units

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Zimmermann, Lisa ; Riesinger, Christoph ; Balázs, Gábor ; Scheer, Manfred
Date of publication of this fulltext: 05 Oct 2023 11:05

This publication is part of the DEAL contract with Wiley.


The reactivity of the mixed dipnictogen complexes [{CpMo(CO)2}2(μ,η2 : 2-PE)] (E=P, As, Sb) towards different group 14 electrophiles is reported. The resulting library of cationic compounds [{CpMo(CO)2}2(μ,η2 : 2-EPR)]+ (R=Mes (2,4,6-C6H2Me3), CH3, CPh3, SnMe3) represents formally inorganic diazonium homologs which are stabilized by transition metal units. Modifying the steric and electronic ...


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