Synthesis and Reactivity of Hetero‐Pnictogen Diazonium Analogs Stabilized by Transition Metal Units

URN to cite this document:: urn:nbn:de:bvb:355-epub-547683
DOI to cite this document:: 10.5283/epub.54768

Zimmermann, Lisa ; Riesinger, Christoph ; Balázs, Gábor

; Scheer, Manfred

License: Creative Commons Attribution Non-commercial No Derivatives 4.0
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Date of publication of this fulltext: 05 Oct 2023 11:05

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Abstract

The reactivity of the mixed dipnictogen complexes [{CpMo(CO)2}2(μ,η2 : 2-PE)] (E=P, As, Sb) towards different group 14 electrophiles is reported. The resulting library of cationic compounds [{CpMo(CO)2}2(μ,η2 : 2-EPR)]+ (R=Mes (2,4,6-C6H2Me3), CH3, CPh3, SnMe3) represents formally inorganic diazonium homologs which are stabilized by transition metal units. Modifying the steric and electronic ...