Asymmetric Photoaerobic Lactonization and Aza-Wacker Cyclization of Alkenes Enabled by Ternary Selenium–Sulfur Multicatalysis

URN to cite this document:: urn:nbn:de:bvb:355-epub-555889
DOI to cite this document:: 10.5283/epub.55588

Lei, Tao ; Graf, Sebastian ; Schöll, Christopher ; Krätzschmar, Felix ; Gregori, Bernhard ; Appleson, Theresa ; Breder, Alexander

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Date of publication of this fulltext: 23 Feb 2024 15:37

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Abstract

An adaptable, sulfur-accelerated photoaerobic selenium-π-acid ternary catalyst system for the enantioselective allylic redox functionalization of simple, nondirecting alkenes is reported. In contrast to related photoredox catalytic methods, which largely depend on olefinic substrates with heteroatomic directing groups to unfold high degrees of stereoinduction, the current protocol relies on ...