Liquid Ammonia: More than an Innocent Solvent for Zintl Anions

URN to cite this document:: urn:nbn:de:bvb:355-epub-588758
DOI to cite this document:: 10.5283/epub.58875

Gärtner, Stefanie

; Witzmann, Michael ; Lorenz-Fuchs, Corinna ; Gschwind, Ruth M.

; Korber, Nikolaus

License: Creative Commons Attribution 4.0
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Date of publication of this fulltext: 14 Aug 2024 13:25

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Abstract

Liquid ammonia as the original solvent for Zintl anions has been replaced by easier to handle or more versatile solvents in most recent Zintl chemistry. However, methodological advances have made it possible to structurally investigate the anions in ammoniate crystals via crystallography or in the solutions themselves via nuclear magnetic resonance. While in some cases liquid ammonia acts as an ...