Enhancing the Reactivity of an Aromatic cyclo‐P5 Ligand via Electrophilic Activation

URN to cite this document:: urn:nbn:de:bvb:355-epub-594603
DOI to cite this document:: 10.5283/epub.59460

Riesinger, Christoph ; Blank, Philip ; Scholtes, Christian ; Gschwind, Ruth M.

; Scheer, Manfred

License: Creative Commons Attribution Non-commercial No Derivatives 4.0
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Date of publication of this fulltext: 05 Nov 2024 05:31

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Abstract

Electrophilic activation of the aromatic cyclo-P5 ligand in [Cp*Fe(h5-P5)] is demonstrated to drastically enhance its reactivity towards weak nucleophiles. Unprecedented functionalized, contracted as well as complexly aggregated polyphosphorus compounds are accessed utilizing [Cp*Fe(h5-P5Me)][OTf] (A), highlighting the great potential of this underexplored mode of reactivity. Addition of carbenes ...