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Cyclen transition metal complexes as biomimetic catalysts, phosphate anion sensors and building-blocks in supramolecular assemblies

URN to cite this document: urn:nbn:de:bvb:355-opus-8902

Woinaroschy, Kristina Michaela (2009) Cyclen transition metal complexes as biomimetic catalysts, phosphate anion sensors and building-blocks in supramolecular assemblies. PhD, Universität Regensburg

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Abstract (English)

This PhD thesis is a study of cyclen transition metal complexes as biomimetic catalysts, phosphate anion sensors and building-blocks in supramolecular assemblies. We have synthesised new Cu(II) and Ni(II) complexes of macrocyclic ligands and compared their hydrolytic properties in aqueous solution towards 4-nitrophenyl acetate and bis(4-nitrophenyl)phosphate with that of identical Zn(II) ...

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Translation of the abstract (German)

Diese Doktorarbeit ist ein Studium über Übergangsmetallkomplexe von Cyclen als biomimetische Katalysatoren, Sensoren von Phosphatanionen und Bausteine für supramolekulare Aggregate. Wir haben neue azamakrocyclische Cu(II) und Ni(II) Komplexe hergestellt, ihre hydrolytische Aktivität gegenüber 4-Nitrophenyl Acetat und Bis(4-Nitrophenyl)Phosphat in wässrigen Lösungen untersucht und mit der von ...

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Export bibliographical data

Item Type:Thesis of the University of Regensburg (PhD)
Date:6 January 2009
Referee:Burkhard (Prof. Dr.) König
Date of exam:27 November 2007
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Keywords:Tetraazacyclododecane , Übergangsmetallkomplexe , Katalysator , Biomimetikum , Supramolekulare Chemie , Phosphate , Anion , Chemischer Sensor , Supramolekularchemie , Cyclen , supramolecular chemistry , cyclen , phosphate anions , metalloenzymes , tetraazole
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Universitätsbibliothek Regensburg
Deposited On:14 Jan 2010 15:22
Last Modified:13 Mar 2014 12:25
Item ID:12077
Owner Only: item control page
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