Hennig, H. and Ritter, K. and Knoll, H. and Vogler, Arnd
Spectrophotometric studies of the photolysis of diazido-bis(phosphine)-metal(II) complexes.
Inorganica Chimica Acta 211 (1), pp. 117-120.
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The photolysis of mixed ligand complexes of the type MLn(N3)2 (M=Ni, Pd, Pt; L = phosphane and diphosphane ligands, respectively; n = 1, 2) was monitored by electronic spectroscopy in absorption, emission and excitation. Initial quantum yields of these complexes were measured in CH2Cl2 and EtOH in dependence on the irradiation wavelength. Photochemically formed MOIn fragments of Pd and Pt are ...
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