Yersin, Hartmut and Strasser, J. (1997) Chemically tuned zero-field splittings and spin-lattice relaxation - Investigation by time-resolved emission. Journal of Luminescence 72-74, pp. 462-463.
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Abstract
For the compounds studied, zero-field splittings (zfs) of the lowest triplets lie between about 0.1 and 200 cm⁻¹. This energy determines spin-lattice relaxation (slr) rates and thus time developments of the emission. It is possible to shift these relaxation
times into pre-defined time regions. The importance of these properties is demonstrated for the representative [Ru(bpy)₃]²⁺.
| Item Type: | Article | ||||
|---|---|---|---|---|---|
| Institutions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Light and Matter) > Prof. Dr. Hartmut Yersin | ||||
| Identification Number: |
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| Keywords: | [Ru(bpy)3]2+; Pt(II) compounds; Zero-field splitting; Spin-lattice relaxation | ||||
| Subjects: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Owner: | Prof. Dr. Hartmut Yersin | ||||
| Deposited On: | 14 Feb 2011 13:34 | ||||
| Last Modified: | 14 Feb 2011 13:34 | ||||
| Item ID: | 17555 |
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