Yersin, Hartmut and Strasser, J. (1997) Chemically tuned zero-field splittings and spin-lattice relaxation - Investigation by time-resolved emission. Journal of Luminescence 72-74, pp. 462-463.
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For the compounds studied, zero-field splittings (zfs) of the lowest triplets lie between about 0.1 and 200 cm⁻¹. This energy determines spin-lattice relaxation (slr) rates and thus time developments of the emission. It is possible to shift these relaxation
times into pre-defined time regions. The importance of these properties is demonstrated for the representative [Ru(bpy)₃]²⁺.
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|Institutions:||Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin|
|Keywords:||[Ru(bpy)3]2+; Pt(II) compounds; Zero-field splitting; Spin-lattice relaxation|
|Dewey Decimal Classification:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Deposited On:||14 Feb 2011 12:34|
|Last Modified:||14 Feb 2011 12:34|