Chemically tuned zero-field splittings and spin-lattice relaxation - Investigation by time-resolved emission

Yersin, Hartmut and Strasser, J. (1997) Chemically tuned zero-field splittings and spin-lattice relaxation - Investigation by time-resolved emission. Journal of Luminescence 72-74, pp. 462-463.

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Abstract

For the compounds studied, zero-field splittings (zfs) of the lowest triplets lie between about 0.1 and 200 cm⁻¹. This energy determines spin-lattice relaxation (slr) rates and thus time developments of the emission. It is possible to shift these relaxation
times into pre-defined time regions. The importance of these properties is demonstrated for the representative [Ru(bpy)₃]²⁺.

Item Type:Article
Institutions: Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Light and Matter) > Prof. Dr. Hartmut Yersin
Identification Number:
ValueType
10.1016/S0022-2313(97)00014-8DOI
Keywords:[Ru(bpy)3]2+; Pt(II) compounds; Zero-field splitting; Spin-lattice relaxation
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner:Prof. Dr. Hartmut Yersin
Deposited On:14 Feb 2011 13:34
Last Modified:14 Feb 2011 13:34
Item ID:17555
Owner Only: item control page