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Facile production of higher hydrocarbons from ethane in a catalytic supersonic nozzle

Shebaro, Lina ; Abbott, Benjamin ; Hong, Theodore ; Slenczka, Alkwin ; Friedrich, Bretislav ; Herschbach, Dudley



Zusammenfassung

Flowing C2H6, typically at 80 Torr, 1000 Deg and 10 ms contact time, through a supersonic nozzle made of Ni or Mo converts roughly 40% to higher hydrocarbons. In the mass spectra of the products, CnHm, the most prominent peaks contain even nos. of C atoms (n = 4, ..., 12), but there are also substantial peaks with odd C-atom nos. (n = 3, ..., 11). The largest peaks have m ~ n H atoms, but many ...

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