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Asymmetric synthesis of chiral-at-metal complexes with pentadentate bis(oxazoline) ligands

Seitz, Michael (2005) Asymmetric synthesis of chiral-at-metal complexes with pentadentate bis(oxazoline) ligands. PhD, Universität Regensburg.

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Date of publication of this fulltext: 04 Jul 2005 06:50

Abstract (English)

A number of novel chiral, pentadentate bis(oxazoline)-pyridine-ligands and the corresponding metal complexes were synthesized. Especially the mononuclear complexes of late transition metals (Mn-Zn) were analyzed with respect to their structures in the solid and the solution state by e.g. NMR-, UV- and CD-spectroscopy. Complex formation proved to be highly diastereoselective in almost every case ...


Translation of the abstract (German)

Eine Reihe von neuen chiralen, fünzähnigen Bisoxazolin-Pyridin-Liganden und deren Metallkomplexe wurden synthetisiert. Im Speziellen die mononuklearen Komplexe von späten Übergangsmetallen (Mn-Zn) wurden hinsichtlich ihrer Struktur im Festkörper und in Lösung mit z.B. NMR-, UV- und CD-Spektroskopie untersucht. Die Komplexbildung verläuft dabei in nahezu allen Fällen hoch diastereoselektiv im ...


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Item type:Thesis of the University of Regensburg (PhD)
Date:3 July 2005
Referee:Oliver (Prof. Dr.) Reiser
Date of exam:15 July 2004
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Keywords:Metallchelate / Chirale Verbindungen , Fünfzähniger Ligand , CD-Spektroskopie , Übergangsmetallkomplexe , Dihydrooxazole , Strukturanalyse , , chiral ligand , bis(oxazoline) , structure determination , stereogenic metal , cd-spectroscopy
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:10273
Owner only: item control page


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