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Synthese und Immobilisierung neuer Azabis(oxazolin)liganden und deren Anwendung in der asymmetrischen Katalyse

URN to cite this document:
urn:nbn:de:bvb:355-opus-6537
DOI to cite this document:
10.5283/epub.10501
Gißibl, Anja
Date of publication of this fulltext: 13 Jun 2007 08:11


Abstract (German)

Die vorliegende Arbeit beinhaltet die Synthese neuer Moleküle der Substanzklasse der Azabis(oxazoline)sowie deren Immobilisierung an verschiedene polymere Träger. Weiterhin wird die Anwendung ihrer Kupferkomplexe in verschiedenen katalytischen Reaktionen wie der asymmetrischen Benzoylierung racemischer 1,2-Diole, der asymmetrischen allylischen Oxidation von Oelfinen und der Michael-Addition von ...

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Translation of the abstract (English)

This thesis contains the synthesis of new Azabis(oxazolines) and their immobilisation to polymeric supports. Their copper complexes were applied as catalysts in several catalytic reactions as the asymmetric benzoylation of racemic 1,2-Diols, the asymmetric allylic oxidation of olefins and the Michael Addition of indoles to alkylidene-malonates. The supported catalysts were reisolated and reused in several catalytic cycles.


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