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Stereoselective synthesis of 1,2-cyclopropanecarboxylated furanoids: applications towards the preparation of marine natural products and unnatural amino acids

URN to cite this document:
urn:nbn:de:bvb:355-opus-7387
Shinde, Yogesh
Date of publication of this fulltext: 02 Jul 2007 08:12


Abstract (English)

The present work was aimed at the development of copper-(I)-bisoxazoline catalyzed cyclopropanation of furans as a key step towards the stereoselective synthesis of a cis-fused furo[2,3-b]furan intermediates which can be broadly applied for the synthesis of spongiane diterpenoids such as norrisolide. Norrisolide was isolated in 1983 by Faulkner, Clardy and coworkers in a study of the chemical ...

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Translation of the abstract (German)

Die vorliegende Arbeit beschreibt die Entwicklung Kupfer(I)-Bisoxazolin katalysierter Cyclopropanierungen von Furanen als Schlüsselschritt der stereoselektiven Synthese von cis-verknüpften Furo[2,3-b]furan Zwischenstufen welche weite Anwendung in der Synthese von Diterpenoiden wie Norrisolid finden. Norrisolid wurde 1983 von Faulkner, Clardy et al. während Studien über das chemische ...

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