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Synthesis of optically active half-sandwich complexes with bidentate and tridentate ligands

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Tsuno, Takashi
Date of publication of this fulltext: 10 Dec 2007 12:10

Abstract (English)

PN ligands 1 and 2, derived from 2-diphenylphosphanylmethylpyridine, were synthesized, to which in the backbone a tether to a cyclopentadiene system and for comparison an iPr substituent were attached. The chiral compounds were resolved by introduction of a menthoxy substituent into the 2-position of the pyridine system. The tripod ligand 1 contains three different binding sites (Cp, P, and N) ...


Translation of the abstract (German)

Die PN-Liganden 1 und 2, abgeleitet von 2-Diphenylphosphanylmethylpyridin, wurden synthetisiert, an die im Rückgrat eine Verbindung zu einem Cyclopentadien-System und zum Vergleich ein iPr-Substituent angehängt wurden. Die chiralen Verbindungen wurden durch Einführung eines Menthoxy-Substituenten in die 2-Position des Pyridin-Systems gespalten. Der Tripod-Ligand 1 enthält drei verschiedene ...


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