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NMR-Detection of Cu(III) Intermediates in Substitution Reactions of Alkyl Halides with Gilman Cuprates

Gärtner, T., Henze, W. and Gschwind, R. M. (2007) NMR-Detection of Cu(III) Intermediates in Substitution Reactions of Alkyl Halides with Gilman Cuprates. Journal of the American Chemical Society 129 (37), pp. 11362-11363.

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Abstract

The first NMR observation of the long-proposed Cu(III) intermediate in a substitution reaction of methylhalides with organocuprates is presented. One-dimensional 1H and HMBC spectra give for the first time direct experimental evidence for a square planar coordination of the Cu(III) intermediate in solution. The presence of 4,4-dimethylcyclohexenone increases the detectable amount of the ...

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Item type:Article
Date:2007
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind
Identification Number:
ValueType
10.1021/ja074788yDOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Partially
Item ID:10629
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