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Controlling the Rate of Shuttling Motions in [2]Rotaxanes by Electrostatic Interactions: A Cation as Solvent-Tunable Brake

Ghosh, P., Federwisch, G., Kogey, M., Schalley, C. A., Haase, D., Saak, W., Lützen, A. and Gschwind, R. M. (2005) Controlling the Rate of Shuttling Motions in [2]Rotaxanes by Electrostatic Interactions: A Cation as Solvent-Tunable Brake. Organic & Biomolecular Chemistry 3 (15), pp. 2691-2700.

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Abstract

A series of rotaxanes, with phenolic axle centerpieces and tetralactam macrocycles as the wheels, has been prepared in good yields. The threaded rotaxane structure is confirmed in the gas phase by tandem mass spectrometric experiments through a detailed fragmentation pattern analysis, in solution by NMR spectroscopy, and in the solid state through X-ray crystallography. A close inspection of the ...

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Item type:Article
Date:2005
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind
Identification Number:
ValueType
10.1039/b506756aDOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Partially
Item ID:10639
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