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Me(2)CuLi*LiCN in diethyl ether prefers a homodimeric core structure [Me(2)CuLi](2) and not a heterodimeric one [Me(2)CuLi*LiCN]: (1)H, (6)Li HOE and (1)H, (1)H NOE studies by NMR

Gschwind, R. M. ; Xie, X. ; Rajamohanan, P. R. ; Auel, C. ; Boche, G.



Abstract

H−Li distances and 1H−1H dipolar interactions in Me2CuLi*LiCN and Me2CuLi in diethyl ether (Et2O), obtained by NMR spectroscopy, were used to gain structural information about the contact ion pair of the salt-containing organocuprate Me2CuLi*LiCN in this solvent. The H−Li distances of Me2CuLi*LiCN and Me2CuLi in Et2O, resulting from the initial buildup rates in conjunction with the motional ...

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