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Development of new methods for the synthesis of pharmacologically active compounds. Synthesis of new immobilized homo- and heterogeneous catalysts for the chemoselective oxidation of alcohols

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Gheorghe, Alexandru
Date of publication of this fulltext: 24 Jan 2008 16:12

Abstract (English)

During this Ph.D. thesis we developed an efficient access to the novel 3,4-didehydropyrohomoglutamate from pyrrole and we developed an extremely simple and practical protocol for grafting TEMPO onto polystyrene resin and perfluorinated supports from readily available and inexpensive starting materials using the "Click Chemistry" asligation method.

Translation of the abstract (German)

Während dieser Promotion haben wir einen effizienten Zugang zu neuen 3,4-Didehydropyrohomoglutamaten aus dem Pyrrol entwickelt, sowie eine sehr einfache und praktische Vorschrift zur Immobilisierung von TEMPO mit verfügbaren und billigen Ausgangsmaterialen anhand von "Click-Chemie".

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