(CuBr)₃P₄Se₄: A low symmetric variant of the (CuI)₃P₄Se₄ structure type

URN to cite this document:: urn:nbn:de:bvb:355-epub-115257
DOI to cite this document:: 10.5283/epub.11525

Nilges, T. ; Reiser, S.

; Pfitzner, Arno

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Date of publication of this fulltext: 07 Jan 2010 09:15

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Abstract

Bright orange (CuBr)(3)P4Se4 is obtained from the reaction of CuBr, P, and Se in stoichiometric amounts (CuBr : P : Se = 3 4 : 4). The composition and the crystal structure of the compound were determined from single crystal X-ray diffraction data. Lattice constants are a = 33.627(2) Angstrom, b = 6.402(1) Angstrom, c = 19.059(1) Angstrom, beta = 90.19(3)degrees, V = 4103.2(3) Angstrom(3), and Z ...