(LiI)₂Li₃SbS₃: A mixed Alkali Metal Halide Thioantimonate with a novel Tetrahedron Network

URN to cite this document:: urn:nbn:de:bvb:355-epub-115278
DOI to cite this document:: 10.5283/epub.11527

Pfitzner, Arno

; Preitschaft, C. ; Rau, F.

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Date of publication of this fulltext: 07 Jan 2010 09:17

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Abstract

(LiL)(2)Li3SbS3 was prepared by solid-state reaction of stoichiometric amounts of Lil, Li, Sb, and S in the ratio 2 : 3 : I : 3. The product is air and moisture sensitive. The crystal structure was determined from single crystals at room temperature. Colourless to pale yellow (Lil)(2)Li3SbS3 crystallizes in the orthorhombic system, space group Pnnm (no. 58) with a = 10.436(l) Angstrom, b = ...