Nb₂Cl₁₀(P₄S₁₀)₂: A co-crystal of Nb₂Cl₁₀ and P₄S₁₀

URN to cite this document:: urn:nbn:de:bvb:355-epub-116847
DOI to cite this document:: 10.5283/epub.11684

Pfitzner, Arno

; Hoppe, Diana

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Date of publication of this fulltext: 25 Feb 2010 06:37

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Abstract

Red moisture-sensitive crystals of Nb2Cl10(P4S10)(2) were obtained from a solution of P4S10 and Nb2Cl10 in CS2. Nb2Cl10(P4S10)(2) crystallises in the space group P (1) over bar with a = 9.577(2), b = 10.894(2), c = 11.477(2) angstrom, alpha = 71.40(1), beta = 68.14(1), gamma = 67.58(1)degrees; V = 1005.2(3) angstrom(3), Z = 2. In the crystal structure molecules of P4S10 and Nb2Cl10 are arranged ...