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(HgBr₂)₃*(As₄S₄)₂: An Adduct of HgBr₂ molecules and undistorted As₄S₄ cages
Bräu, Michael and Pfitzner, Arno
(2007)
(HgBr₂)₃*(As₄S₄)₂: An Adduct of HgBr₂ molecules and undistorted As₄S₄ cages.
Zeitschrift für anorganische und allgemeine Chemie (633), pp. 935-937.
Date of publication of this fulltext: 23 Dec 2009 11:23
Article
DOI to cite this document: 10.5283/epub.11690
Abstract
(HgBr2)(3)(AS(4)S(4))(2) is obtained by high temperature reaction of stoichiometric amounts of HgBr2 and AS4S4. It crystallizes in the monoclinic space group P2(1)/c with the lattice constants a = 9.593(5) angstrom, b = 11.395(5) angstrom, c = 13.402(5) angstrom, beta = 107.27(3)degrees, V = 1399(1) angstrom(3), and Z = 2. The crystal structure consists of molecular units built from two ...
(HgBr2)(3)(AS(4)S(4))(2) is obtained by high temperature reaction of stoichiometric amounts of HgBr2 and AS4S4. It crystallizes in the monoclinic space group P2(1)/c with the lattice constants a = 9.593(5) angstrom, b = 11.395(5) angstrom, c = 13.402(5) angstrom, beta = 107.27(3)degrees, V = 1399(1) angstrom(3), and Z = 2. The crystal structure consists of molecular units built from two undistorted AS(4)S(4) cages which are coordinated weakly by three almost linear HgBr2 units. Raman spectra clearly indicate minor bonding interactions between HgBr2 and AS(4)S(4).
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| Item type | Article | ||||
| Journal or Publication Title | Zeitschrift für anorganische und allgemeine Chemie | ||||
| Publisher: | WILEY-V C H VERLAG GMBH | ||||
|---|---|---|---|---|---|
| Place of Publication: | WEINHEIM | ||||
| Number of Issue or Book Chapter: | 633 | ||||
| Page Range: | pp. 935-937 | ||||
| Date | 2007 | ||||
| Institutions | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Arno Pfitzner | ||||
| Identification Number |
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| Keywords | CRYSTAL-STRUCTURE; COPPER IODIDE; SPECTROSCOPIC CHARACTERIZATION; MERCURY; HALIDES; (CUI)(3)P4SE4; POLYMER; FAMILY; SCREWS; CHAINS; mercury halides; molecular adducts; arsenic sulfides; crystal structures; Raman spectroscopy | ||||
| Dewey Decimal Classification | 500 Science > 540 Chemistry & allied sciences | ||||
| Status | Published | ||||
| Refereed | Yes, this version has been refereed | ||||
| Created at the University of Regensburg | Unknown | ||||
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-116904 | ||||
| Item ID | 11690 |
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