(HgBr₂)₃*(As₄S₄)₂: An Adduct of HgBr₂ molecules and undistorted As₄S₄ cages

URN to cite this document:: urn:nbn:de:bvb:355-epub-116904
DOI to cite this document:: 10.5283/epub.11690

Bräu, Michael ; Pfitzner, Arno

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Date of publication of this fulltext: 23 Dec 2009 11:23

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Abstract

(HgBr2)(3)(AS(4)S(4))(2) is obtained by high temperature reaction of stoichiometric amounts of HgBr2 and AS4S4. It crystallizes in the monoclinic space group P2(1)/c with the lattice constants a = 9.593(5) angstrom, b = 11.395(5) angstrom, c = 13.402(5) angstrom, beta = 107.27(3)degrees, V = 1399(1) angstrom(3), and Z = 2. The crystal structure consists of molecular units built from two ...