Ring-shaped [(TiCl₂)(1,3-P₂S₈)]₂ molecules containing uncommon P₂S₈²⁻ anions

URN to cite this document:: urn:nbn:de:bvb:355-epub-116977
DOI to cite this document:: 10.5283/epub.11697

Hoppe, Diana ; Pfitzner, Arno

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Date of publication of this fulltext: 23 Dec 2009 11:24

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Abstract

Intensely red, moisture-sensitive crystals of [(TiCl2)(1,3-P2S8)](2) were obtained by the reaction of TiCl4 and P4S10 at room temperature. The crystal structure determination revealed molecules formally consisting of two units of the anion [1,3-P2S8](2-) connected with two [TiCl2](2+) cations resulting in the ring-shaped [(TiCl2)(1,3-P2S8)](2). The thiophosphate [1,3-P2S8](2-) forms a ...