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Ring-shaped [(TiCl₂)(1,3-P₂S₈)]₂ molecules containing uncommon P₂S₈²⁻ anions
Hoppe, Diana and Pfitzner, Arno
(2009)
Ring-shaped [(TiCl₂)(1,3-P₂S₈)]₂ molecules containing uncommon P₂S₈²⁻ anions.
Zeitschrift für anorganische und allgemeine Chemie (635), pp. 1986-1990.
Date of publication of this fulltext: 23 Dec 2009 11:24
Article
DOI to cite this document: 10.5283/epub.11697
Abstract
Intensely red, moisture-sensitive crystals of [(TiCl2)(1,3-P2S8)](2) were obtained by the reaction of TiCl4 and P4S10 at room temperature. The crystal structure determination revealed molecules formally consisting of two units of the anion [1,3-P2S8](2-) connected with two [TiCl2](2+) cations resulting in the ring-shaped [(TiCl2)(1,3-P2S8)](2). The thiophosphate [1,3-P2S8](2-) forms a ...
Intensely red, moisture-sensitive crystals of [(TiCl2)(1,3-P2S8)](2) were obtained by the reaction of TiCl4 and P4S10 at room temperature. The crystal structure determination revealed molecules formally consisting of two units of the anion [1,3-P2S8](2-) connected with two [TiCl2](2+) cations resulting in the ring-shaped [(TiCl2)(1,3-P2S8)](2). The thiophosphate [1,3-P2S8](2-) forms a six-membered ring and has a rather uncommon constitution among the multitude of anionic phosphorus sulfides and selenides.
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| Item type | Article | ||||
| Journal or Publication Title | Zeitschrift für anorganische und allgemeine Chemie | ||||
| Publisher: | WILEY-BLACKWELL | ||||
|---|---|---|---|---|---|
| Place of Publication: | MALDEN | ||||
| Number of Issue or Book Chapter: | 635 | ||||
| Page Range: | pp. 1986-1990 | ||||
| Date | 2009 | ||||
| Institutions | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Arno Pfitzner | ||||
| Identification Number |
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| Keywords | CRYSTAL-STRUCTURE; TITANIUM TETRACHLORIDE; ADDITION COMPOUNDS; SULFUR PHOSPHORUS; METAL HALIDES; COORDINATION; CHEMISTRY; CHLORIDE; SELENIUM; ADDUCTS; | ||||
| Dewey Decimal Classification | 500 Science > 540 Chemistry & allied sciences | ||||
| Status | Published | ||||
| Refereed | Yes, this version has been refereed | ||||
| Created at the University of Regensburg | Unknown | ||||
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-116977 | ||||
| Item ID | 11697 |
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