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Cu₂MnMIVS₄ (MIV = Si, Ge, Sn) - crystal structures and tetrahedra volumes of normal tetrahedral compounds
Bernert, Thomas und Pfitzner, Arno
(2005)
Cu₂MnMIVS₄ (MIV = Si, Ge, Sn) - crystal structures and tetrahedra volumes of normal tetrahedral compounds.
Zeitschrift für Kristallographie – New Crystal Structures (220), S. 968-972.
Veröffentlichungsdatum dieses Volltextes: 22 Mrz 2010 06:55
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.11741
Zusammenfassung
The crystal structures of the normal tetrahedral compounds Cu2MnSiS4, Cu2MnGeS4, and Cu2MnSnS4 are presented. The structures were refined from single crystal X-ray data. Cu2MnSiS4 and Cu2MnGeS4 crystallize in the space group Pmn2(1) in a wurtzite type superstructure. The refinement Of Cu2MnSiS4 converged to R = 0.0214 and wR2 = 0.0477. The redetennination of Cu2MnGeS4 converged to R = 0.0281, wR2 ...
The crystal structures of the normal tetrahedral compounds Cu2MnSiS4, Cu2MnGeS4, and Cu2MnSnS4 are presented. The structures were refined from single crystal X-ray data. Cu2MnSiS4 and Cu2MnGeS4 crystallize in the space group Pmn2(1) in a wurtzite type superstructure. The refinement Of Cu2MnSiS4 converged to R = 0.0214 and wR2 = 0.0477. The redetennination of Cu2MnGeS4 converged to R = 0.0281, wR2 = 0.0739. The tetrahedra volumes of the coordination polyhedra of the cations in these compounds are calculated and compared with those of Cu2MnSnS4 (redetermination, spacegroup I (4) over bar 2m, sphalerite type superstructure, R = 0.0146, wR2 = 0.0425). In the wurtzite type structures the tetrahedra volumes differ significantly for different cations while they differ only in a small range in the sphalerite type structure.
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| Dokumentenart | Artikel | ||||
| Titel eines Journals oder einer Zeitschrift | Zeitschrift für Kristallographie – New Crystal Structures | ||||
| Verlag: | WALTER DE GRUYTER GMBH | ||||
|---|---|---|---|---|---|
| Ort der Veröffentlichung: | BERLIN | ||||
| Nummer des Zeitschriftenheftes oder des Kapitels: | 220 | ||||
| Seitenbereich: | S. 968-972 | ||||
| Datum | 2005 | ||||
| Institutionen | Chemie und Pharmazie > Institut für Anorganische Chemie > Lehrstuhl Prof. Dr. Arno Pfitzner | ||||
| Identifikationsnummer |
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| Stichwörter / Keywords | MAGNETIC-PROPERTIES; tetrahedral structures; quaternary copper chalcogenides; Wurtzite structure type; sphalerite structure type; single crystal structure analysis; X-ray diffraction | ||||
| Dewey-Dezimal-Klassifikation | 500 Naturwissenschaften und Mathematik > 540 Chemie | ||||
| Status | Veröffentlicht | ||||
| Begutachtet | Ja, diese Version wurde begutachtet | ||||
| An der Universität Regensburg entstanden | Unbekannt / Keine Angabe | ||||
| URN der UB Regensburg | urn:nbn:de:bvb:355-epub-117410 | ||||
| Dokumenten-ID | 11741 |
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