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Bernert, Thomas ; Pfitzner, Arno

Cu₂MnMIVS₄ (MIV = Si, Ge, Sn) - crystal structures and tetrahedra volumes of normal tetrahedral compounds

Article

Bernert, Thomas and Pfitzner, Arno (2005) Cu₂MnMIVS₄ (MIV = Si, Ge, Sn) - crystal structures and tetrahedra volumes of normal tetrahedral compounds. Zeitschrift für Kristallographie – New Crystal Structures (220), pp. 968-972.

DOI to cite this document: 10.5283/epub.11741


Abstract

The crystal structures of the normal tetrahedral compounds Cu2MnSiS4, Cu2MnGeS4, and Cu2MnSnS4 are presented. The structures were refined from single crystal X-ray data. Cu2MnSiS4 and Cu2MnGeS4 crystallize in the space group Pmn2(1) in a wurtzite type superstructure. The refinement Of Cu2MnSiS4 converged to R = 0.0214 and wR2 = 0.0477. The redetennination of Cu2MnGeS4 converged to R = 0.0281, wR2 ...

The crystal structures of the normal tetrahedral compounds Cu2MnSiS4, Cu2MnGeS4, and Cu2MnSnS4 are presented. The structures were refined from single crystal X-ray data. Cu2MnSiS4 and Cu2MnGeS4 crystallize in the space group Pmn2(1) in a wurtzite type superstructure. The refinement Of Cu2MnSiS4 converged to R = 0.0214 and wR2 = 0.0477. The redetennination of Cu2MnGeS4 converged to R = 0.0281, wR2 = 0.0739. The tetrahedra volumes of the coordination polyhedra of the cations in these compounds are calculated and compared with those of Cu2MnSnS4 (redetermination, spacegroup I (4) over bar 2m, sphalerite type superstructure, R = 0.0146, wR2 = 0.0425). In the wurtzite type structures the tetrahedra volumes differ significantly for different cations while they differ only in a small range in the sphalerite type structure.



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Details

Item typeArticle
Journal or Publication TitleZeitschrift für Kristallographie – New Crystal Structures
PublisherWALTER DE GRUYTER GMBH
Place of PublicationBERLIN
Number of Issue or Book Chapter220
Page Rangepp. 968-972
Date2005
Date of publication22 Mar 2010 06:55
InstitutionsChemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Arno Pfitzner
Identification Number
ValueType
10.1524/zkri.2005.220.11_2005.968DOI
KeywordsMAGNETIC-PROPERTIES; tetrahedral structures; quaternary copper chalcogenides; Wurtzite structure type; sphalerite structure type; single crystal structure analysis; X-ray diffraction
Dewey Decimal Classification500 Science > 540 Chemistry & allied sciences
StatusPublished
RefereedYes, this version has been refereed
Created at the University of RegensburgUnknown
URN of the UB Regensburgurn:nbn:de:bvb:355-epub-117410
Item ID11741

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