Extending the time: Solvothermal syntheses, crystal structures and properties of two not isostructural thioantimonates with the composition [Mn(tren)]Sb₂S₄

URN to cite this document:: urn:nbn:de:bvb:355-epub-117865
DOI to cite this document:: 10.5283/epub.11786

Schaefer, Michael ; Kurowski, Daniel ; Pfitzner, Arno

; Näther, Christian ; Rejai, Zomaje ; Möller, Karina ; Ziegler, Nancy ; Bensch, Wolfgang

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Date of publication of this fulltext: 23 Dec 2009 11:36

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Abstract

The two novel compounds, [Mn(tren)]Sb2S4 (1 and 2), were obtained by the reaction of elemental Mn, Sb, and S in aqueous solutions of tren (tren = tris(2-aminoethyl)amine, C6H18N4) after different reaction times. Compound 1 is formed up to a reaction time of 13 d, and an extension of the reaction time leads to the formation of 2. Both compounds crystallize in monoclinic space groups (1, P2(1)/c, ...