(CuBr)₂P₈Se₃: Preparation, Structural, and Vibrational Spectroscopic Characterization of an Adduct of P₈Se₃ Cages to Cu₂Br₂ Rhombs

URN to cite this document:: urn:nbn:de:bvb:355-epub-118329
DOI to cite this document:: 10.5283/epub.11832

Nilges, S.

; Nilges, T.

; Haeuseler, H. ; Pfitzner, Arno

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Date of publication of this fulltext: 23 Dec 2009 11:39

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Abstract

Orange-red (CuBr)(2)P8Se3 was obtained from stoichiometric amounts of CuBr, P and Se by melting and subsequent annealing at 380 degreesC for 1 month. The crystal structure was determined from single crystal X-ray data. (CuBr)(2)P8Se3 crystallizes in the orthorhombic system, space group Pbcm (No. 57), with a = 8.761(1) Angstrom, b = 11.957(1) Angstrom, c = 13.858(1) Angstrom, V = 1451.8(3) ...