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Synthesis, characterization and application of alpha-beta-oligopeptides as bifunctional organocatalysts for the aldol reaction

URN to cite this document:
urn:nbn:de:bvb:355-opus-11669
D'Elia, Valerio
Date of publication of this fulltext: 24 Feb 2010 09:16


Abstract (English)

Although the idea of using substoichiometric amounts of organic molecules to promote chemical transformations may look obvious and reminiscent of the natural activity of many enzymes, only few, scattered reports appeared in this field before that List and Barbas showed proline´s ability to catalyze the asymmetric intermolecular aldol reaction. The rigid beta-aminocyclopropanecarboxylic acids have ...

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Translation of the abstract (German)

During the current decade organocatalysis1 has met an unprecedented interest. Während des letzten Jahrzehnts stieß die Organokatalyse auf ein nie zuvor dagewesenes Interesse. Obwohl die Idee substoichiometrische Mengen organischer Moleküle zu nutzen, um chemische Reaktionen zu beschleunigen, offensichtlich zu sein scheint und an die natürliche Aktivität vieler Enzyme erinnert, erschienen nur ...

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