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Outer-Sphere Ligand to Ligand Charge Transfer of Metal Complexes

URN to cite this document:
urn:nbn:de:bvb:355-epub-133366
DOI to cite this document:
10.5283/epub.13336
Vogler, Arnd ; Kunkely, Horst
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Date of publication of this fulltext: 17 Mar 2010 06:15


Abstract

The electronic spectra of the salts [NiII(tim)]2+[MII(mnt)2(t]i2m- = 2,3,9,1O-tetramethyl-l,4,8,11 -tetra-azacyclotetradeca-
1,3,8,10-tetraener H2mnt = 1,2-dicyano-l ,2-ethylenedithiolI M2+ = Ni2+, Pd2+, Pt2+) are dominated by an
intense absorption band which is assigned to an outer-sphere ligand to ligand charge transfer transition from the
complex anion to the cation.


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