| PDF (2MB) |
- URN to cite this document:
- urn:nbn:de:bvb:355-epub-133394
- DOI to cite this document:
- 10.5283/epub.13339
Abstract
The photochemistry of the following azide complexes in organic solvents has been investigated: [Au(N3)4]⁻, [Au(N3)2]⁻, [Ag(PPh3)2N3], [Pt(N3)6]2⁻, [Pt(N3)4]2⁻, [Pd(N3)4]2⁻, and [Pd2(N3)6]2⁻. All complexes underwent a photochemical reduction of the metal and oxidation of azide upon ligand to metal charge transfer excitation. The photolysis of the complexes with the metals in the lower oxidation ...
Owner only: item control page
Download Statistics