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Photochemistry of Azide Complexes of Gold, Silver, Platinum and Palladium. Generation of the Metallic State

URN to cite this document:
urn:nbn:de:bvb:355-epub-133394
DOI to cite this document:
10.5283/epub.13339
Vogler, Arnd ; Quett, C. ; Kunkely, Horst
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Date of publication of this fulltext: 15 Mar 2010 06:23


Abstract

The photochemistry of the following azide complexes in organic solvents has been investigated: [Au(N3)4]⁻, [Au(N3)2]⁻, [Ag(PPh3)2N3], [Pt(N3)6]2⁻, [Pt(N3)4]2⁻, [Pd(N3)4]2⁻, and [Pd2(N3)6]2⁻. All complexes underwent a photochemical reduction of the metal and oxidation of azide upon ligand to metal charge transfer excitation. The photolysis of the complexes with the metals in the lower oxidation ...

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