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Photochemistry of [MCo₂(CO)₈] (M=Zn, Cd, Hg) induced by metal to metal charge transfer excitation

URN to cite this document:
Vogler, Arnd ; Kunkely, Horst
Date of publication of this fulltext: 15 Mar 2010 06:22


The electronic absorption spectra of the complexes [(OC),Co-‘M”Co-‘(CO),] with M = Zn, Cd, and Hg display an intense long-wavelength band which is assigned to the allowed Σu+ -> Σg+ transition from a non-bonding σ to an antibonding σ orbital of the Co-M-Co moiety. This transition is shifted to higher energies and gains an increasing charge transfer (CT) contribution in changing M in the order M = ...


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