Go to content
UR Home

Photoredox Reaction of [Cr(CO)₅I] induced by Ligand to Metal Charge Transfer Excitation

URN to cite this document:
urn:nbn:de:bvb:355-epub-133448
DOI to cite this document:
10.5283/epub.13344
Kunkely, Horst ; Vogler, Arnd
[img]
Preview
PDF
(224kB)
Date of publication of this fulltext: 15 Mar 2010 06:21


Abstract

The complex [CrI(CO)5I] is characterized by a long-wavelength absorption at λmax 638 nm. This band is assigned to a ligand to metal charge transfer (LMCT) transition from iodide (π) to CrI (t2g). Upon LMCT excitation the complex undergoes a photoredox reaction with a quantum yield φ 0.01 according to the equation: [CrI(CO)5I] + CH3CN → [Cr0(CO)5CH3CN] + I/2 I2. This reaction takes place also thermally.


Owner only: item control page
  1. Homepage UR

University Library

Publication Server

Contact:

Publishing: oa@ur.de

Dissertations: dissertationen@ur.de

Research data: daten@ur.de

Contact persons