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Absorption and emission spectra of tetrameric gold(I) complexes

URN to cite this document:
urn:nbn:de:bvb:355-epub-133453
Vogler, Arnd ; Kunkely, Horst
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Date of publication of this fulltext: 15 Mar 2010 06:32


Abstract

The lowest-energy absorption and emisson bands of the complexes [Au(dithioacetate)]4 and [Au(piperidine)Cl]4 are assigned to a metal-centered 5d-6s (A2g↔1g) transition which is modified by the metal-metal interaction in the square-planar Au(I)4 moiety.


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