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Photoluminescence of Tetranuclear Mercury(II) Complexes

URN to cite this document:
urn:nbn:de:bvb:355-epub-133485
DOI to cite this document:
10.5283/epub.13348
Kunkely, Horst ; Vogler, Arnd
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Date of publication of this fulltext: 15 Mar 2010 06:28


Abstract

The complexes [Hg4(SPh)6(PPh3)4]2+ and [Hg(2-pyridylphenyl)Cl]4 show an intense low-temperature (77 K) phosphorescence at λmax=690 and 500 nm. This emission is assumed to originate from a metal-centered ds excited state which contains considerable ligand-to-metal charge transfer character.


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