Optical Ligand to Ligand Charge Transfer of Metal Complexes Including Ligand-Based Mixed-Valence Systems

URN to cite this document:: urn:nbn:de:bvb:355-epub-135048
DOI to cite this document:: 10.5283/epub.13504

Vogler, Arnd ; Kunkely, Horst

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Date of publication of this fulltext: 17 Mar 2010 06:14

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Abstract

The electronic spectra of metal complexes which contain a reducing and an oxidizing ligand (Lred-M-Lox) are characterized by ligand to ligand charge transfer (LLCT) absorptions. A specific form of Lred-M-Lox complexes are ligand-based mixed-valence (LBMV) compounds which contain the same ligand in two different redox states. In this case the ligand-ligand interaction may lead to a partial or even ...