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Luminescence of Dimeric T1(I) Complexes: Metal-Metal Interaction in the Electronically Excited State

URN to cite this document:
urn:nbn:de:bvb:355-epub-135093
DOI to cite this document:
10.5283/epub.13509
Sabin, F. ; Vogler, Arnd
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Date of publication of this fulltext: 17 Mar 2010 06:12


Abstract

Dimeric diethyldithiocarbamatethallium(I) [Et 2NCS2Tl]2 shows a red emission at λmax=608 nm which undergoes a huge Stokes shift with regard to the excitation maximum at λ=246 nm. It is suggested that the emission originates from a sp excited state which is characterized by strong metal-metal bonding.


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