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Photochemistry and Photophysics of Coordination Compounds of the Main Group Metals

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Vogler, Arnd ; Nikol, H.
Date of publication of this fulltext: 17 Mar 2010 06:11


The photoproperties of main group metal complexes with the electron
configurations s2 (e.g. T l + , Sb3 + , Te4 + ) and s° (e.g. T l 3 + , Pb4 + ) were studied on the
basis of a general concept which relates characteristic excited states to typical
photophysical and photochemical processes. The photochemistry is dominated by metalcentered
sp (s2) and ligand to metal charge transfer (s°) excited states which are capable
of inducing inter- and intramolecular redox reactions.

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